Material Safety Data Sheet: Fluorine Bromine (FBr)

Identification

Product Name: Fluorine Bromine
Chemical Formula: FBr
Synonyms: Bromine monofluoride
Recommended Use: Laboratory reagent, specialty chemical synthesis
Manufacturer/Distributor: Industrial chemical supplier
Emergency Phone: Local emergency response
CAS Number: 7789-25-5

Hazard Identification

Classification: Oxidizing gas, highly toxic by inhalation, corrosive to tissues
Hazard Statements: Causes severe burns to skin and eyes, inhaling vapors can lead to fatal lung injury, highly reactive
Signal Word: Danger
Pictograms: Corrosion, skull and crossbones, gas cylinder, flame over circle
Precautionary Statements: Avoid breathing fumes or gas, wear full protective gear, keep away from combustibles, use only outdoors or in a fume hood

Composition / Information on Ingredients

Chemical Name: Fluorine Bromine
Percent: 100%
Molecular Weight: 98.90 g/mol
Impurities: May contain trace hydrogen fluoride or bromine as byproducts

First Aid Measures

Inhalation: Remove to fresh air immediately, provide oxygen if breathing is difficult, seek emergency medical help
Skin Contact: Strip contaminated clothes, flush skin with running water for at least 15 minutes, seek medical attention without delay
Eye Contact: Rinse eyes continuously with water for no less than 20 minutes, call physician urgently
Ingestion: Unlikely exposure route, do not induce vomiting, call poison center immediately, give nothing by mouth
Symptoms: Severe irritation, burns, coughing, chest pain, pulmonary edema, possible fatalities from acute exposure

Fire-Fighting Measures

Suitable Extinguishing Media: Large volumes of water in deluge form, do not use dry chemical or carbon dioxide
Special Hazards: Reacts violently with organics, releases toxic fumes, supports combustion by supplying oxidizer
Protective Equipment: Positive pressure self-contained breathing apparatus (SCBA), full chemical suit
Firefighting Actions: Approach from upwind, evacuate area, cool containers from safe distance

Accidental Release Measures

Personal Precautions: Evacuate unprotected personnel, ventilate area, do not touch spilled material
Environmental Precautions: Prevent entry to sewers, waterways, or soil, alert local authorities
Spill Response: Use water spray to knock down vapors, dilute spill with copious water if safe, neutralize with soda ash after dilution, avoid breathing vapors or allowing contact with combustibles

Handling and Storage

Handling: Use only in ventilated chemical fume hoods, keep respirators and emergency gear nearby, avoid mechanical shock or compression, never mix with acids or organics
Storage: Store in corrosion-resistant containers made for halogen gases, isolate from incompatibles, keep cool and dry, secure cylinders upright, ensure cylinder valves are tightly closed

Exposure Controls and Personal Protection

Occupational Exposure Limits: No OSHA PEL established, ACGIH TLV 0.1 ppm as F2
Engineering Controls: Local exhaust, explosion-proof ventilation, gas detection sensors
PPE: Positive pressure SCBA, chemical-resistant gloves (nitrile or stronger), fully encapsulating suit, face shield, safety glasses, rubber boots
Hygiene Measures: Remove contaminated clothing, wash hands and face thoroughly after handling, do not eat or drink in work area

Physical and Chemical Properties

Appearance: Colorless to pale yellow gas
Odor: Pungent, suffocating
Boiling Point: –6 °C (21 °F)
Melting Point: –73 °C (–99 °F)
Vapor Pressure: Very high at 20 °C
Solubility: Hydrolyzes in water
Density: 3.5 kg/m³ (gas at 0°C, 1 atm)
Other: Highly reactive, attacks glass, metals, and organic materials

Stability and Reactivity

Chemical Stability: Breaks down in light, heat, or moisture
Incompatible Materials: Organic substances, metals, reducing agents, glass, water, acids
Hazardous Decomposition: Yields hydrogen fluoride, bromine, various halogenated acids under decomposition
Reactivity: Rapidly reacts with organic matter, causes violent exothermic reactions, very strong oxidizer

Toxicological Information

Acute Toxicity: Extremely toxic by inhalation (LC50 values for related halogens are in low ppm range for 1 hour exposure)
Chronic Effects: Prolonged or repeated exposure may result in dental and skeletal fluorosis, chronic lung conditions
Routes of Exposure: Inhalation, skin/eye contact
Target Organs: Respiratory system, skin, mucous membranes
Symptoms: Severe coughing, choking, tissue destruction, delayed pulmonary edema
Carcinogenicity: Not classified by IARC, NTP, or OSHA

Ecological Information

Environmental Toxicity: Harmful to aquatic life due to acidification and oxidizing properties
Persistence and Degradability: Highly reactive, does not persist in environment, hydrolyzes rapidly
Bioaccumulation: Not likely due to instability
Other Adverse Effects: Alters pH of water, destroys living tissues on contact, can devastate local flora and fauna if released

Disposal Considerations

Waste Treatment Methods: Neutralize slowly and safely with dilute alkali under fume hood, use water scrubbing system for gas releases, contain and dispose in accordance with federal, state, and local regulations
Packaging Disposal: Rinse containers thoroughly, neutralize residues before disposal, treat packaging as hazardous waste if contaminated

Transport Information

UN Number: UN2198
UN Proper Shipping Name: Bromine Fluoride, Compressed
Transport Hazard Class: 2.3 (toxic gas), 5.1 (oxidizer)
Packing Group: Not Applicable (gases)
Special Provisions: Keep cylinders upright and secured, transport only with certified hazardous materials carriers, emergency response guide provided
Labels Required: Toxic Gas, Oxidizer

Regulatory Information

TSCA Status: Listed
SARA Title III: Section 302 Extremely Hazardous Substance
CERCLA: Subject to spill reporting, RQ 10 lbs for similar halogens
OSHA: Process safety management may apply
State Regulations: May be subject to additional state and local reporting
International: Covered under international transport and chemical safety laws