MSDS for 2-Bromoethylamine Hydrobromide

Identification

Product Name: 2-Bromoethylamine Hydrobromide
Synonyms: 2-Bromoethanamine hydrobromide, Bromoethylamine HBr
CAS Number: 2576-47-8
Molecular Formula: C2H7Br2N
Molecular Weight: 221.90 g/mol
Recommended Use: Laboratory chemicals, synthesis intermediate
Manufacturer Information: Check chemical container label for supplier details and emergency phone numbers

Hazard Identification

GHS Classification: Acute toxicity (Oral) Category 3, Skin corrosion/irritation Category 2, Serious eye damage/eye irritation Category 2A
Signal Word: Danger
Hazard Statements: Toxic if swallowed, causes skin irritation, causes serious eye irritation
Pictograms: Skull and crossbones, exclamation mark
Precautionary Statements: Avoid exposure, wash hands thoroughly after handling, wear protective clothing, do not eat, drink, or smoke while using this product, keep container tightly closed, use in a well-ventilated area

Composition / Information on Ingredients

Chemical Name: 2-Bromoethylamine Hydrobromide
Concentration: 98-100%
CAS Number: 2576-47-8
Impurities and Stabilizing Additives: No additional hazardous ingredients known, purity usually above 98%

First Aid Measures

General Advice: Move exposed person to fresh air immediately and keep safe
If Inhaled: Remove from area, seek medical attention if symptoms develop, give artificial respiration if not breathing
If On Skin: Remove contaminated clothing, wash skin with soap and plenty of water, seek medical advice if irritation develops
If In Eyes: Rinse cautiously with water for several minutes, seek immediate medical attention
If Swallowed: Do not induce vomiting, rinse mouth, seek medical attention without delay
Most Important Symptoms: Burning eyes, skin redness, respiratory tract irritation, gastrointestinal discomfort
Notes to Physician: Provide symptomatic and supportive care, monitor patient for complications

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide
Specific Hazards: Thermal decomposition may release hazardous fumes including hydrogen bromide, nitrogen oxides, carbon oxides
Protective Equipment: Wear full protective gear, self-contained breathing apparatus
Firefighting Procedures: Keep containers cool with water spray, prevent firewater from entering drains or water bodies, approach fire from upwind side

Accidental Release Measures

Personal Precautions: Wear personal protective equipment including gloves, safety goggles, suitable clothing, avoid dust formation
Environmental Precautions: Prevent entry into sewers, waterways, soil, alert authorities if significant release occurs
Methods for Cleaning Up: Sweep carefully, avoid dust, collect into suitable containers, ventilate area, wash area after pickup, dispose according to local regulations

Handling and Storage

Precautions for Safe Handling: Minimize dust and vapor generation, handle in fume hood, use appropriate PPE, avoid skin and eye contact, ensure accessible eyewash stations
Conditions for Safe Storage: Keep container tightly sealed, store in cool, dry, ventilated area, keep away from incompatible substances like strong oxidizers and acids, store away from food and drinks, label containers clearly

Exposure Controls and Personal Protection

Control Parameters: No occupational exposure limits established for this compound
Engineering Controls: Use fume hood and local exhaust ventilation, regularly monitor working area
Personal Protective Equipment: NIOSH/MSHA approved respirator if dust or vapor exists, chemical resistant gloves, lab coat or apron, safety goggles, avoid using contact lenses, provide eyewash and shower stations nearby
Hygiene Measures: Wash hands after handling, do not eat, drink, or smoke where this chemical is used, change contaminated clothing promptly

Physical and Chemical Properties

Appearance: White to slightly off-white crystalline powder
Odor: Not characterized, may be slight amine-like
Odor Threshold: Not available
pH: Not determined (aqueous solutions may be acidic)
Melting Point: 208 - 212°C
Boiling Point: Decomposes before boiling
Flash Point: Not available
Evaporation Rate: Not applicable
Flammability: Not classified as flammable
Vapor Pressure: Not available
Solubility: Soluble in water
Partition Coefficient: Not determined
Viscosity: Not applicable
Decomposition Temperature: Above melting point, decomposes to toxic gases
Density: Not established

Stability and Reactivity

Chemical Stability: Stable under standard conditions
Possibility of Hazardous Reactions: Reacts with strong oxidizers, acids, sensitive to moisture
Incompatible Materials: Strong acids, oxidizing agents, strong bases
Hazardous Decomposition Products: Hydrogen bromide gas, nitrogen oxides, carbon oxides
Conditions to Avoid: Excess heat, moisture, sources of ignition, open flames, incompatible materials

Toxicological Information

Acute Toxicity: Harmful if swallowed, inhaled, or absorbed through skin; LD50 data: oral rat ~100 mg/kg
Skin Corrosion/Irritation: Causes skin irritation, prolonged contact intensifies damage
Serious Eye Damage/Irritation: Causes significant irritation, risk of permanent injury
Respiratory Sensitization: May cause respiratory tract irritation
Skin Sensitization: Not known to be a sensitizer
Carcinogenicity: Not classified by ACGIH, NTP, IARC
Reproductive Toxicity: Not established
Other Effects: Gastrointestinal discomfort, headaches, drowsiness, coughing, wheezing possible with exposure

Ecological Information

Ecotoxicity: Harmful to aquatic organisms, risk of long-term adverse effects in the aquatic environment
Mobility in Soil: Water soluble, may leach into soil and groundwater
Persistence and Degradability: Not readily biodegradable under environmental conditions
Bioaccumulation Potential: Not expected to bioaccumulate significantly
Other Adverse Effects: Spills may alter local pH and introduce toxic bromine-containing compounds to ecosystems

Disposal Considerations

Waste Treatment Methods: Dispose through licensed chemical waste contractor
Waste Codes: Consult local, state, and federal regulations for proper waste identification
Disposal Precautions: Do not pour into drains, sewers, or environment
Contaminated Packaging: Clean containers can be recycled after proper decontamination, otherwise dispose as hazardous waste
Additional Notes: Handle all waste as potentially hazardous

Transport Information

UN Number: 2811
UN Proper Shipping Name: Toxic solid, organic, n.o.s. (2-Bromoethylamine hydrobromide)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Marine Pollutant: Not listed as a marine pollutant
Special Precautions: Package securely, label correctly, provide emergency contact on shipping documents, restrict public access during transport

Regulatory Information

TSCA Status: Listed on the inventory
DSL/NDSL (Canada): Listed/Non-listed status must be checked with supplier
EINECS/ELINCS (EU): Listed
SARA Title III: Not listed under Section 302, 304, 313
California Proposition 65: Not listed
Other Regulations: Comply with all regional, national, and local regulations governing chemical usage, storage, and disposal; handle with attention to worker training, labeling, and personal protection rules