Product Name: 2-Bromoaniline
Chemical Formula: C6H6BrN
CAS Number: 615-36-1
Synonyms: o-Bromoaniline, o-Aminobromobenzene
Recommended Use: Intermediate for organic syntheses, dyes, pharmaceuticals
Manufacturer and Contact: Available on manufacturer website or shipping documents
GHS Classification: Acute toxicity (oral, dermal, inhalation), skin irritation, eye damage
Pictograms: Skull and crossbones, exclamation mark
Signal Word: Danger
Hazard Statements: Harmful if swallowed, causes skin and eye irritation, may cause respiratory irritation, harmful to aquatic life
Precautionary Statements: Avoid breathing dust, wash thoroughly after handling, use protective gear, avoid release to environment
Potential Health Effects: Inhalation may cause coughing, dizziness, headaches; skin exposure may lead to redness, swelling, and dermatitis
Chemical Name: 2-Bromoaniline
Percentage by Weight: >98%
Impurities & Additives: Trace organic compounds (<2%)
Other Ingredients: None listed
Inhalation: Remove person to fresh air, keep at rest, consult a physician if symptoms persist
Skin Contact: Wash with plenty of soap and water, remove contaminated clothing, seek medical advice for persistent irritation
Eye Contact: Rinse cautiously with water for several minutes, remove contacts, continue rinsing, seek medical help if irritation continues
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical attention
Symptoms & Effects: Burning sensation, headaches, nausea, respiratory discomfort
Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray
Specific Hazards: Toxic fumes of nitrogen oxides, hydrogen bromide, carbon monoxide and carbon dioxide from combustion
Protective Equipment: Fire fighters need self-contained breathing apparatus and full protective gear
Firefighting Advice: Move containers from fire area if safe, cool exposed containers with water spray to prevent rupture
Explosion Data: Not considered an explosion hazard but may emit toxic gases under high heat
Personal Precautions: Avoid contact with skin, eyes, prevent inhalation of dust or fumes
Emergency Procedures: Evacuate unprotected personnel, ventilate area, use fully-sealed protective wear
Environmental Precautions: Avoid entry into sewers, soil, waterways; alert local authorities if large spills occur
Containment: Scoop up solid material, sweep up without creating dust, place in suitable closed container
Cleanup: Clean residue with damp absorbent material, ventilate afterward
Handling: Prevent skin and eye contact, avoid inhalation of dust or vapors, use in a fume hood or well-ventilated area, wash hands after handling, do not eat or drink during use
Storage Requirements: Store securely in tightly closed containers, keep cool and dry, avoid exposure to sunlight, separate from acids and oxidizers, follow local regulatory storage guidelines
Incompatible Materials: Oxidizing agents, strong acids
Safe Transfer: Transfer in controlled areas with adequate ventilation and spill protection
Exposure Limits: No official occupational exposure limit established, use caution and minimize all exposure
Engineering Controls: Chemical fume hood, local exhaust ventilation
Personal Protective Equipment: Chemical-resistant gloves, splash goggles or face shield, long-sleeved lab coat, closed footwear, use of respiratory protection if ventilation is insufficient
Hygiene Measures: Shower and change clothes after handling, keep workspaces clean, prohibit eating, drinking or smoking near material
Appearance: Off-white to light brown crystalline solid
Odor: Aromatic, unpleasant
Melting Point: 31-33°C
Boiling Point: 243-245°C
Density: 1.6 g/cm³ at 20°C
Solubility: Slightly soluble in water, soluble in ethanol and ether
Vapor Pressure: Negligible at room temperature
pH: Not available (insoluble in water)
Flash Point: >110°C (closed cup)
Autoignition Temperature: Data not available
Stability: Stable under recommended storage conditions
Partition Coefficient (Log Kow): Approx. 2.1
Stability: Chemically stable if stored as recommended
Reactivity: Reacts with strong oxidizers, acids
Hazardous Decomposition Products: Hydrogen bromide, nitrogen oxides, carbon oxides on heating or combustion
Polymerization: Not known to occur
Conditions to Avoid: Heat, flames, open sources of ignition, contact with incompatible materials
Acute Toxicity: Oral LD50 (rat) ~1000 mg/kg; may cause blood and organ changes in high doses
Inhalation: May cause respiratory tract irritation, headaches, nausea
Skin Contact: Can cause redness, pain, long exposure increases risk of dermatitis
Eye Contact: Irritation, redness, tearing
Chronic Effects: Prolonged exposure may lead to liver, kidney, blood effects
Carcinogenicity: Not classified as a carcinogen by NTP, IARC, OSHA
Sensitization: No sensitization data available
Mutagenicity: Limited data, handle as a potential mutagen
Acute Aquatic Toxicity: Harmful to fish and aquatic organisms; EC50 and LC50 values in low mg/L range for typical aquatic testing species
Persistence and Degradability: Not rapidly biodegradable, may persist in environment
Bioaccumulative Potential: Moderate potential based on Log Kow value
Soil Mobility: Not mobile in soil, binds to organic matter
Other Information: Avoid uncontrolled release, environmental monitoring may be required for large releases
Disposal Methods: Collect and deliver waste to certified hazardous chemical disposal facility, comply with local and national regulations
Product Disposal: Incinerate in approved facility with flue gas scrubber, avoid landfill
Contaminated Packaging: Rinse thoroughly and dispose as hazardous waste, do not reuse
Precautions: Prevent substance release to drains or public waterways
UN Number: 2810
UN Proper Shipping Name: Toxic liquid, organic, n.o.s. (2-Bromoaniline)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Environmental Hazards: Harmful to aquatic environment
Special Transport Precautions: Securely packed, labeled, protect containers from physical damage, only trained personnel should handle shipment
US TSCA Inventory: Listed
EU REACH Status: Required registration, subject to REACH regulations
Canadian DSL/NDSL: Present on DSL
Labelling Requirements: Conform to GHS, OSHA Hazard Communication, and local regulations
Other International Regulations: May be subject to region-specific chemical reporting and safety legislation
Worker Protection: Follow OSHA and workplace chemical hygiene plans
