Material Safety Data Sheet: 1-Chlorodecane

Identification

Product Name: 1-Chlorodecane
Chemical Formula: C10H21Cl
Synonyms: Decyl chloride
CAS Number: 112-85-6
Recommended Use: Laboratory chemical, ingredient in chemical synthesis
Supplier: (Company details, contact information, emergency phone number)

Hazard Identification

Classification: Flammable liquid, Irritant
Hazard Statements: Causes skin and eye irritation; harms aquatic life; flammable liquid and vapor
Pictograms: Flame, exclamation mark, environment
Precautionary Statements: Keep away from heat, sparks, open flames; avoid contact with eyes and skin; use protective equipment; wash thoroughly after handling
Other Hazards: Vapors heavier than air; may displace oxygen in enclosed spaces

Composition / Information on Ingredients

Chemical Name: 1-Chlorodecane
Concentration: ≥ 98%
Impurities: Decane, isomeric chlorinated decanes, aliphatic hydrocarbons (trace amounts)

First Aid Measures

Inhalation: Move individual to fresh air; consult a physician if symptoms develop; provide oxygen if breathing is difficult
Skin Contact: Remove contaminated clothing; rinse skin with plenty of water for 15 minutes; seek medical advice for persistent irritation
Eye Contact: Rinse eyes with water for at least 15 minutes, lifting eyelids occasionally; seek immediate medical attention
Ingestion: Never give anything by mouth to an unconscious person; do not induce vomiting; rinse mouth with water and seek immediate medical attention
Symptoms of Exposure: Itching, redness, coughing, dizziness, respiratory discomfort

Fire-Fighting Measures

Suitable Extinguishing Media: Alcohol-resistant foam, dry chemical, carbon dioxide, water spray for cooling containers
Unsuitable Extinguishing Media: Direct water jet
Special Hazards: Emits toxic fumes (hydrogen chloride, carbon monoxide) if burned
Advice for Firefighters: Wear self-contained breathing apparatus, full protective gear, prevent run-off from entering waterways
Specific Methods: Remove containers from fire zone if possible; keep containers cool with water spray

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate, prevent inhalation of vapors, use full protective gear
Environmental Precautions: Prevent from reaching drains, waterways, soil; inform authorities if large spill threatens environment
Containment: Absorb with earth, sand, inert material
Cleaning Up: Use non-sparking tools, collect in suitable container, dispose as hazardous waste, wash area with soap and water

Handling and Storage

Handling: Work in well-ventilated area; avoid breathing vapor; prevent contact with skin and eyes; keep container tightly closed; use proper grounding and bonding when transferring
Storage: Store below 25°C in a cool, dry, well-ventilated place; keep away from ignition sources, oxidizers, acids; store in original or compatible container clearly labeled
Incompatible Materials: Strong oxidizers, strong acids, bases; avoid contact with reactive metals

Exposure Controls and Personal Protection

Control Parameters: No established occupational exposure limits for 1-Chlorodecane
Engineering Controls: Fume hood or local exhaust ventilation required in handling areas; keep airborne concentrations below exposure guidelines
Personal Protection: Chemical safety goggles, face shield, impervious gloves, protective clothing, suitable respirator if ventilation is inadequate
Hygiene Measures: Remove contaminated clothing, wash after handling, never eat, drink or smoke while working with the chemical

Physical and Chemical Properties

Appearance: Clear, colorless liquid
Odor: Mild characteristic odor
Odor Threshold: Not established
pH: Not applicable
Melting Point/Freezing Point: -34°C
Boiling Point/Range: 224–226°C
Flash Point: ~94°C (closed cup)
Evaporation Rate: Slow
Flammability: Combustible
Explosion Limits: Lower: Data not available, Upper: Data not available
Vapor Pressure: 0.2 mmHg at 25°C
Vapor Density: >1 (air = 1)
Relative Density: 0.870–0.880 (water = 1)
Solubility: Insoluble in water; miscible with organic solvents
Partition Coefficient (n-octanol/water): Not known
Auto-ignition Temperature: Not established
Decomposition Temperature: Data unavailable
Viscosity: Thin liquid

Stability and Reactivity

Stability: Stable under normal conditions and storage in tightly closed containers
Reactivity: Reacts with strong oxidizers, acids, bases; formation of toxic fumes possible in contact with hot surfaces or open flame
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, phosgene (under fire conditions)
Polymerization: Does not occur

Toxicological Information

Routes of Exposure: Inhalation, skin and eye contact, ingestion
Acute Toxicity: Oral LD50 (rat) > 2000 mg/kg (estimated); no reliable data on inhalation or dermal LD50
Skin Corrosion/Irritation: Causes irritation
Serious Eye Damage/Irritation: Causes eye irritation
Respiratory Issues: Vapors may cause respiratory tract irritation
Chronic Effects: Long-term exposure may affect liver, kidneys; data limited on carcinogenicity
Other Effects: No evidence of mutagenicity or reproductive toxicity in available studies

Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms; LC50 (fish, 96h): not available; may cause long-lasting harmful effects
Mobility in Soil: Not readily mobile; strongly adsorbed onto soil particles
Persistence and Degradability: Not readily biodegradable
Bioaccumulation Potential: High potential due to low water solubility and high octanol/water coefficient
Other Adverse Effects: May contribute to long-term pollution in aquatic environments

Disposal Considerations

Waste Disposal: Collect and dispose as hazardous chemical waste; use licensed waste contractor
Disposal Methods: Incineration in accordance with local, regional, national, and international regulations
Contaminated Packaging: Decontaminate containers prior to disposal; treat as hazardous waste
Precautions: Avoid release to environment; do not dispose in drains, soil or natural waterways

Transport Information

UN Number: 3082
UN Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (1-Chlorodecane)
Transport Hazard Class: 9 (Miscellaneous hazardous substances)
Packing Group: III
Environmental Hazards: Marine pollutant
Special Precautions: Handle according to local regulations, ensure secure packaging, keep away from food and animal feeds

Regulatory Information

TSCA Status: Listed on the US Toxic Substances Control Act (TSCA) inventory
DSL Status: Listed on Canadian Domestic Substances List (DSL)
REACH Registration: Registered under relevant European regulations, requires user notification for certain activities
Label Elements: According to GHS – pictograms, signal words, hazard statements included
Other regulations: Subject to workplace safety, environmental release, and transportation regulations in most jurisdictions